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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">vguit</journal-id><journal-title-group><journal-title xml:lang="ru">Вестник Воронежского государственного университета инженерных технологий</journal-title><trans-title-group xml:lang="en"><trans-title>Proceedings of the Voronezh State University of Engineering Technologies</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2226-910X</issn><issn pub-type="epub">2310-1202</issn><publisher><publisher-name>VSUET</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.20914/2310-1202-2021-4-232-237</article-id><article-id custom-type="elpub" pub-id-type="custom">vguit-2923</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Химическая технология</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>Fundamental and Applied chemistry, chemical technology</subject></subj-group></article-categories><title-group><article-title>Разработка сорбционного материала на основе модифицированных алюмосиликатов с высокой адсорбционной способностью по отношению к сероводороду</article-title><trans-title-group xml:lang="en"><trans-title>Development of sorption material based on modified alumosilicates with high adsorption ability to hydro sulfur.</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-4869-5855</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Свиридов</surname><given-names>А. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Sviridov</surname><given-names>A. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>к.т.н., доцент, кафедра химической технологии древесины, биотехнологии и наноматериалов, Сибирский тракт, 37, г. Екатеринбург, 620100, Россия</p></bio><bio xml:lang="en"><p>Cand. Sci. (Engin.), associate professor, chemical technology of wood, biotechnology and nanomaterials department, 37 Sibirsky Trakt, Ekaterinburg, 620100, Russia</p></bio><email xlink:type="simple">asv1972@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0003-2905-569X</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Юрченко</surname><given-names>В. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Yurchenko</surname><given-names>V. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>ст. преподаватель, кафедра химической технологии древесины, биотехнологии и наноматериалов, Сибирский тракт, 37, г. Екатеринбург, 620100, Россия</p></bio><bio xml:lang="en"><p>senior lecturer, chemical technology of wood, biotechnology and nanomaterials department, 37 Sibirsky Trakt, Ekaterinburg, 620100, Russia</p></bio><email xlink:type="simple">navijoy@inbox.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-4057-7846</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Гиндулин</surname><given-names>И. К.</given-names></name><name name-style="western" xml:lang="en"><surname>Gindulin</surname><given-names>I. K.</given-names></name></name-alternatives><bio xml:lang="ru"><p>к.т.н., доцент, кафедра химической технологии древесины, биотехнологии и наноматериалов, Сибирский тракт, 37, г. Екатеринбург, 620100, Россия</p></bio><bio xml:lang="en"><p>Cand. Sci. (Engin.), associate professor, chemical technology of wood, biotechnology and nanomaterials department, 37 Sibirsky Trakt, Ekaterinburg, 620100, Russia</p></bio><email xlink:type="simple">gindulinik@m.usfeu.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-5194-8374</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Каменченко</surname><given-names>Е. А.</given-names></name><name name-style="western" xml:lang="en"><surname>Kamenchenko</surname><given-names>E. A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>инженер, кафедра химической технологии древесины, биотехнологии и наноматериалов, 620100, РФ, Уральский федеральный округ, Свердловская область, г.Екатеринбург, Сибирский тракт, 37</p></bio><bio xml:lang="en"><p>engineer, chemical technology of wood, biotechnology and nanomaterials department, 620100, RF, Ural Federal District, Sverdlovsk Region, Yekaterinburg, Siberian tract, 37</p></bio><email xlink:type="simple">katya.patrick@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Уральский государственный лесотехнический университет</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Ural State Forest Engineering University</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2021</year></pub-date><pub-date pub-type="epub"><day>24</day><month>05</month><year>2025</year></pub-date><volume>83</volume><issue>4</issue><fpage>232</fpage><lpage>237</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Свиридов А.В., Юрченко В.В., Гиндулин И.К., Каменченко Е.А., 2022</copyright-statement><copyright-year>2022</copyright-year><copyright-holder xml:lang="ru">Свиридов А.В., Юрченко В.В., Гиндулин И.К., Каменченко Е.А.</copyright-holder><copyright-holder xml:lang="en">Sviridov A.V., Yurchenko V.V., Gindulin I.K., Kamenchenko E.A.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://www.vestnik-vsuet.ru/vguit/article/view/2923">https://www.vestnik-vsuet.ru/vguit/article/view/2923</self-uri><abstract><p>В работе рассмотрена возможность применения высокодисперсных модифицированных алюмосиликатов в процессе извлечения сероводорода из сточных вод. Проблема наличия сероводорода в природных водах обусловлена невозможностью применения таких вод в хозяйственно-бытовой деятельности человека. Вода с высоким содержанием сероводорода обладает низкими органолептическими свойствами, не пригодна для употребления и обладает высокой коррозионной активностью. Подтоварная вода, образующаяся в процессе нефтедобычи, так же должна быть обработана. При наличии сероводорода в подтоварной воде крайне не рекомендуется дальнейшая закачка воды в пласт, так как это может привести к «закупориванию» нефтеносных каналов. В связи с этим в работе предложен способ извлечения сероводорода из природных и сточных вод. В работе синтезирован новый адсорбционно-коагуляционный материал на основе модифицированных алюмосиликатов (бентонитовых глин) с помощью солей многоволентных металлов. Рассмотрена возможность создания реагента с различным соотношением алюмосиликатная матрица: модификатор. Установлено, что эффективность работы реагента увеличивается с повышением pH среды. Изучалась активность реагента по отношению к сероводороду, осветлению и удалению нефтепродуктов. Емкость полученных в результате модификации реагентов может достигать 32 мг/г по сероводороду. В реагенте возможно варьировать соотношение алюмосиликатов и модификаторов, что может способствовать использованию наиболее эффективного реагента в зависимости от условий. Реагент способен извлекать не только сероводород, но и нефтепродукты из обрабатываемых водных растворов. Реагент связывает сероводород в нерастворимые формы после чего осадок возможно отделить от раствора и утилизировать.</p></abstract><trans-abstract xml:lang="en"><p>The paper considers the possibility of using highly dispersed modified aluminosilicates in the process of extracting hydrogen sulfide from wastewater. The problem of the presence of hydrogen sulfide in natural waters is due to the impossibility of using such waters in human household activities. Water with a high content of hydrogen sulphide has low organoleptic properties, is not suitable for consumption and is highly corrosive. Produced water generated in the process of oil production must also be treated. In the presence of hydrogen sulphide in the produced water, further water injection into the reservoir is highly discouraged, as this can lead to "plugging" of oil-bearing channels. In this regard, the work proposes a method for extracting hydrogen sulfide from natural and waste waters. The work synthesized a new adsorption-coagulation material based on modified aluminosilicates (bentonite clays) using salts of multivalent metals. The possibility of creating a reagent with a different ratio of aluminosilicate matrix: modifier is considered. It was found that the efficiency of the reagent increases with an increase in the pH of the medium. The activity of the reagent in relation to hydrogen sulfide, clarification and removal of oil products was studied. The capacity of the reagents obtained as a result of the modification can reach 32 mg/g in terms of hydrogen sulfide. In the reagent, it is possible to vary the ratio of aluminosilicates and modifiers, which can facilitate the use of the most effective reagent, depending on the conditions. The reagent is capable of extracting not only hydrogen sulfide, but also oil products from the processed aqueous solutions. The reagent binds hydrogen sulfide into insoluble forms, after which the precipitate can be separated from the solution and disposed of.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>коагулянты</kwd><kwd>адсорбция</kwd><kwd>очистка воды</kwd><kwd>модифицированные алюмосиликаты</kwd><kwd>сероводород</kwd></kwd-group><kwd-group xml:lang="en"><kwd>coagulants</kwd><kwd>adsorption</kwd><kwd>water treatment</kwd><kwd>modified aluminosilicates</kwd><kwd>hydrogen sulfide.</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Санитарные правила и нормы СанПиН 2.1.3684–21 "Санитарно-эпидемиологические требования к содержанию территорий городских и сельских поселений, к водным объектам, питьевой воде и питьевому водоснабжению населения, атмосферному воздуху, почвам, жилым помещениям, эксплуатации производственных, общественных помещений, организации и проведению санитарно-противоэпидемических (профилактических) мероприятий"</mixed-citation><mixed-citation xml:lang="en">Sanitary rules and norms SanPiN 2.1.3684-21 "Sanitary and epidemiological requirements for the maintenance of territories of urban and rural settlements, for water bodies, drinking water and drinking water supply of the population, atmospheric air, soils, residential premises, operation of industrial, public premises, organizations and carrying out sanitary and anti-epidemic (preventive) measures". (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Косиченко Ю.М., Сильченко В.Ф. Технологии удаления сероводорода в процессе обработки подземных вод. // Экология и водное хозяйство. 2020. № 1. С. 43–59.</mixed-citation><mixed-citation xml:lang="en">Kosichenko Yu.M., Silchenko V.F. Technologies for the removal of hydrogen sulfide in the process of groundwater treatment. Ecology and water management. 2020. no. 1. pp. 43–59. (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Гузенко М.В. Химические методы очистки сточных вод // Непрерывная система образования. Инновации и перспективы Сборник статей международной студенческой конференции. 2020. С. 238–240.</mixed-citation><mixed-citation xml:lang="en">Gouzenko M.V. Chemical methods of wastewater treatment. Continuous education system. Innovations and prospects Collection of articles of the international student conference. 2020. pp. 238–240. (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Седлухо Ю.П., Станкевич Ю.О. Исследование процесса биохимической очистки подземных вод от сероводорода // Наука и техника. 2015. № 2. С. 55–61.</mixed-citation><mixed-citation xml:lang="en">Sedlukho Yu.P., Stankevich Yu.O. Study of the process of biochemical purification of groundwater from hydrogen sulfide. Science and Technology. 2015. no. 2. pp. 55–61. (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Яблокова М.А., Иваненко А.Ю., Турыгин В.Ю. Очистка подтоварных вод нефтеприисков с целью повторной закачки в нефтеносные пласты для поддержания внутрипластового давления // Известия санкт-петербургского государственного технологического института (технического университета). 2012. № 14. С 78–84.</mixed-citation><mixed-citation xml:lang="en">Yablokova M.A., Ivanenko A.Yu., Turygin V.Yu. Purification of commercial waters of oil fields for the purpose of re-injection into oil-bearing strata to maintain in-situ pressure. Bulletin of the St. Petersburg State Technological Institute (Technical University). 2012. no. 14. pp 78–84. (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Новоселов М.Г., Белканова М.Ю. Технологический анализ работы установки обратного осмоса на подземном водозаборе // Вестник южно-уральского государственного университета. Серия: строительство и архитектура. 2021. Т. 21. № 2. С. 60–68.</mixed-citation><mixed-citation xml:lang="en">Novoselov M.G., Belkanova M.Yu. Technological analysis of the operation of a reverse osmosis unit at an underground water intake. Bulletin of the South Ural State University. Series: construction and architecture. 2021. vol. 21. no. 2. pp. 60–68. (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">ОСТ 39–225–88 Вода для заводнения нефтяных пластов. Требования к качеству.</mixed-citation><mixed-citation xml:lang="en">OST 39–225–88 Water for flooding oil reservoirs. quality requirements. (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Свиридов А.В., Никифоров А.Ф., Ганебных Е.В., Елизаров В.А. Очистка сточных вод от меди природным и модифицированным монтмориллонитом // Водное хозяйство России, 2011. № 1. С. 58–65.</mixed-citation><mixed-citation xml:lang="en">Sviridov A.V., Nikiforov A.F., Ganebnykh E.V., Elizarov V.A. Purification of wastewater from copper with natural and modified montmorillonite. Water Management of Russia, 2011. no. 1. pp. 58–65. (in Russian).</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Ганебных Е.В., Свиридов А.В., Мальцев Г.И. Извлечение цинка из растворов высокодисперсными модифицированными алюмосиликатами // Химия в интересах устойчивого развития. 2015. Т. 23. № 1. С. 89–95.</mixed-citation><mixed-citation xml:lang="en">Ganebnykh E.V., Sviridov A.V., Maltsev G.I. Extraction of zinc from solutions with highly dispersed modified aluminosilicates. Chemistry for Sustainable Development. 2015. vol. 23. no. 1. pp. 89–95</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Krupskaya V. Novikova L., Tyupina E. et al. The influence of acid modification on the structure of montmorillonites and surface properties of bentonites // Applied Clay Science. 2019. V. 172. P. 1–10. doi: 10.1016/j.clay.2019.02.001</mixed-citation><mixed-citation xml:lang="en">Krupskaya V. Novikova L., Tyupina E. et al. The influence of acid modification on the structure of montmorillonites and surface properties of bentonites. Applied Clay Science. 2019. vol. 172. pp. 1–10. doi: 10.1016/j.clay.2019.02.001</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Ali I., Kon'kova T., Kasianov V., Rysev A. et al. Preparation and characterization of nano-structured modified montmorillonite for dioxidine antibacterial drug removal in water // Journal of Molecular Liquids. 2021. V. 331. P. 115770. doi: 10/1016/j.moliq.2021.115770</mixed-citation><mixed-citation xml:lang="en">Ali I., Kon'kova T., Kasianov V., Rysev A. et al. Preparation and characterization of nano-structured modified montmorillonite for dioxidine antibacterial drug removal in water. Journal of Molecular Liquids. 2021. vol. 331. pp. 115770. doi: 10/1016/j.moliq.2021.115770</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Tokar??kov? M., Bardo?ov? L., Seidlerov? J., Drob?kov? K. et al. Magnetically modified montmorillonite-characterisation, sorption properties and stability // Materials Today: Proceedings. 2021. V. 37. P. 48-52. doi: 10.1016/j.matpr.2020.08.721</mixed-citation><mixed-citation xml:lang="en">Tokar??kov? M., Bardo?ov? L., Seidlerov? J., Drob?kov? K. et al. Magnetically modified montmorillonite-characterisation, sorption properties and stability. Materials Today: Proceedings. 2021. vol. 37. pp. 48-52. doi: 10.1016/j.matpr.2020.08.721</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Cao X. et al. CuFe2O4 supported on montmorillonite to activate peroxymonosulfate for efficient ofloxacin degradation // Journal of Water Process Engineering. 2021. V. 44. P. 102359.</mixed-citation><mixed-citation xml:lang="en">Cao X. et al. CuFe2O4 supported on montmorillonite to activate peroxymonosulfate for efficient ofloxacin degradation. Journal of Water Process Engineering. 2021. vol. 44. pp. 102359.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Wu S. et al. Effect of ?-Fe2O3 nanoparticles on the composition of montmorillonite and its sorption capacity for pyrene // Science of The Total Environment. 2021. P. 151893.</mixed-citation><mixed-citation xml:lang="en">Wu S. et al. Effect of ?-Fe2O3 nanoparticles on the composition of montmorillonite and its sorption capacity for pyrene. Science of The Total Environment. 2021. pp. 151893.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Wang J. et al. Impact of montmorillonite clay on the homo-and heteroaggregation of titanium dioxide nanoparticles (nTiO2) in synthetic and natural waters // Science of The Total Environment. 2021. V. 784. P. 147019.</mixed-citation><mixed-citation xml:lang="en">Wang J. et al. Impact of montmorillonite clay on the homo-and heteroaggregation of titanium dioxide nanoparticles (nTiO2) in synthetic and natural waters. Science of The Total Environment. 2021. vol. 784. pp. 147019.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Li Q., Li R., Shi W. Cation adsorption at permanently (montmorillonite) and variably (quartz) charged mineral surfaces: Mechanisms and forces from subatomic scale // Applied Clay Science. 2021. V. 213. P. 106245.</mixed-citation><mixed-citation xml:lang="en">Li Q., Li R., Shi W. Cation adsorption at permanently (montmorillonite) and variably (quartz) charged mineral surfaces: Mechanisms and forces from subatomic scale. Applied Clay Science. 2021. vol. 213. pp. 106245.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Yotsuji K. et al. Effect of interlayer cations on montmorillonite swelling: Comparison between molecular dynamic simulations and experiments // Applied Clay Science. 2021. V. 204. P. 106034.</mixed-citation><mixed-citation xml:lang="en">Yotsuji K. et al. Effect of interlayer cations on montmorillonite swelling: Comparison between molecular dynamic simulations and experiments. Applied Clay Science. 2021. vol. 204. pp. 106034.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Du X. et al. Adsorption of CH4, N2, CO2, and their mixture on montmorillonite with implications for enhanced hydrocarbon extraction by gas injection // Applied Clay Science. 2021. V. 210. P. 106160.</mixed-citation><mixed-citation xml:lang="en">Du X. et al. Adsorption of CH4, N2, CO2, and their mixture on montmorillonite with implications for enhanced hydrocarbon extraction by gas injection. Applied Clay Science. 2021. vol. 210. pp. 106160.</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Pei H., Zhang S. Molecular dynamics study on the zeta potential and shear plane of montmorillonite in NaCl solutions // Applied Clay Science. 2021. V. 212. P. 106212.</mixed-citation><mixed-citation xml:lang="en">Pei H., Zhang S. Molecular dynamics study on the zeta potential and shear plane of montmorillonite in NaCl solutions. Applied Clay Science. 2021. vol. 212. pp. 106212.</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Qin C. et al. Physicochemical properties, metal availability and bacterial community structure in heavy metal-polluted soil remediated by montmorillonite-based amendments // Chemosphere. 2020. V. 261. P. 128010.</mixed-citation><mixed-citation xml:lang="en">Qin C. et al. Physicochemical properties, metal availability and bacterial community structure in heavy metal-polluted soil remediated by montmorillonite-based amendments. Chemosphere. 2020. vol. 261. pp. 128010.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
