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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">vguit</journal-id><journal-title-group><journal-title xml:lang="ru">Вестник Воронежского государственного университета инженерных технологий</journal-title><trans-title-group xml:lang="en"><trans-title>Proceedings of the Voronezh State University of Engineering Technologies</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2226-910X</issn><issn pub-type="epub">2310-1202</issn><publisher><publisher-name>VSUET</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.20914/2310-1202-2025-1-272-279</article-id><article-id custom-type="elpub" pub-id-type="custom">vguit-3599</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Химическая технология</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>Fundamental and Applied chemistry, chemical technology</subject></subj-group></article-categories><title-group><article-title>Влияние наночастиц оксида циркония (ZrО2) на механические, барьерные и антибактериальные свойства полиэтиленовой матрицы</article-title><trans-title-group xml:lang="en"><trans-title>Effect of Zirconium oxide (ZrО2) Nanoparticles on the Mechanical, WVTR, and Antibacterial Properties of Polyethylene Polymer Matrix</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-0871-787X</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Мелессе</surname><given-names>Имру Й.</given-names></name><name name-style="western" xml:lang="en"><surname>Melesse</surname><given-names>Emiru Yidnekachew</given-names></name></name-alternatives><bio xml:lang="en"><p>Department of Industrial Design Packaging Technologies and Expertise</p></bio><email xlink:type="simple">emydms12@gmail.com</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-9518-7781</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Альхаир</surname><given-names>Али Я.</given-names></name><name name-style="western" xml:lang="en"><surname>Alkhair</surname><given-names>Ali Yakoub</given-names></name></name-alternatives><bio xml:lang="en"><p>Department of Industrial Design Packaging Technologies and Expertise</p></bio><email xlink:type="simple">alkheerali@gmail.com</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-2307-6046</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Филинская</surname><given-names>Ю. А.</given-names></name><name name-style="western" xml:lang="en"><surname>Filinskaya</surname><given-names>Y. A.</given-names></name></name-alternatives><bio xml:lang="en"><p>Department of Industrial Design Packaging Technologies and Expertise</p></bio><email xlink:type="simple">FilinskayaYA@mgupp.ru</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0003-3370-4226</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Кирш</surname><given-names>И. А.</given-names></name><name name-style="western" xml:lang="en"><surname>Kirsh</surname><given-names>I. A.</given-names></name></name-alternatives><bio xml:lang="en"><p>Department of Industrial Design Packaging Technologies and Expertise</p></bio><email xlink:type="simple">irina-kirsh@ya.ru</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0003-0633-0003</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Банникова</surname><given-names>О. А.</given-names></name><name name-style="western" xml:lang="en"><surname>Bannikova</surname><given-names>O. A.</given-names></name></name-alternatives><bio xml:lang="en"><p>Department of Industrial Design Packaging Technologies and Expertise</p></bio><email xlink:type="simple">irina-kirsh@ya.ru</email><xref ref-type="aff" rid="aff-2"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Российский биотехнологический университет</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Federal State Budgetary Educational Institution of Higher Education Russian Biotechnological University</institution><country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>Российский биотехнологический университет</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Federal State Budgetary Educational Institution of Higher Education Russian Biotechnology University</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2025</year></pub-date><pub-date pub-type="epub"><day>03</day><month>06</month><year>2025</year></pub-date><volume>87</volume><issue>1</issue><fpage>272</fpage><lpage>279</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Мелессе И.Й., Альхаир А.Я., Филинская Ю.А., Кирш И.А., Банникова О.А., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Мелессе И.Й., Альхаир А.Я., Филинская Ю.А., Кирш И.А., Банникова О.А.</copyright-holder><copyright-holder xml:lang="en">Melesse E.Y., Alkhair A.Y., Filinskaya Y.A., Kirsh I.A., Bannikova O.A.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://www.vestnik-vsuet.ru/vguit/article/view/3599">https://www.vestnik-vsuet.ru/vguit/article/view/3599</self-uri><abstract><p>Методом экструзии с одношнековым смесителем был синтезирован нанокомпозит на основе матрицы из полиэтилена низкой плотности (ПЭНП), армированного наночастицами диоксида циркония (ZrO₂). Проведено комплексное исследование структурных, механических, барьерных и антимикробных свойств полученных пленок. Методами цифровой микроскопии и ИК-Фурье спектроскопии подтверждено наличие наночастиц ZrO₂ с характеристическими колебаниями связи Zr-O при 421, 418 и 468 см⁻¹ для концентраций 4,7; 6,7 и 8,7% мас. соответственно. Механические испытания выявили концентрационно-зависимое снижение прочности на растяжение (с 12,30±0,32 МПа до 8,5±0,4 МПа), относительного удлинения при разрыве (с 482±49,65% до 320±35%) и модуля упругости (с 116±42,3 МПа до 75±20 МПа), что связано с агломерацией наночастиц при повышенных концентрациях. При этом наблюдалось пропорциональное увеличение толщины пленок и улучшение барьерных свойств, выражающееся в снижении скорости передачи водяного пара (WVTR) и коэффициента паропроницаемости (WVP). Нанокомпозиты продемонстрировали выраженную антимикробную активность в отношении Bacillus subtilis и Escherichia coli: при содержании ZrO₂ 8,7% мас. количество колониеобразующих единиц (КОЕ) снизилось на 82% и 90% соответственно. Дополнительные исследования методом ДСК показали повышение температуры термического разложения на 15°C без ухудшения технологических свойств расплава. Полученные результаты свидетельствуют, что введение наночастиц ZrO₂ позволяет направленно модифицировать механические, барьерные и антимикробные характеристики ПНП, что открывает перспективы их применения в активной упаковке пищевых продуктов, требующей контроля влагопроницаемости и микробиологической безопасности. Оптимальное сочетание функциональных свойств достигнуто при содержании наночастиц 6,7% мас.</p></abstract><trans-abstract xml:lang="en"><p>A nanocomposite based on a low-density polyethylene (LDPE) matrix reinforced with zirconium dioxide (ZrO₂) nanoparticles was synthesized via single-screw extrusion and systematically characterized. Structural analysis confirmed homogeneous dispersion of ZrO₂ nanoparticles at lower concentrations (4.7% w/w), while agglomeration occurred at higher loadings (8.7% w/w), as evidenced by digital microscopy. FTIR spectroscopy revealed Zr-O vibrational modes at 421-468 cm⁻¹, verifying successful incorporation. Mechanical properties exhibited concentration-dependent behavior: tensile strength decreased by 31% (12.30→8.5 MPa) and elongation by 34% (482→320%) with 8.7% ZrO₂, attributed to stress concentration at nanoparticle clusters. Conversely, film thickness increased linearly (R²=0.98) with filler content, reducing water vapor transmission rate by 42% through enhanced tortuosity. The nanocomposites demonstrated remarkable antimicrobial efficacy, achieving 3-log reduction against E. coli at 8.7% loading, surpassing conventional food packaging materials. Thermal analysis (DSC/TGA) revealed improved thermal stability (↑15°C in decomposition temperature) without compromising LDPE's melt processability. These findings position ZrO₂-LDPE nanocomposites as advanced materials for active packaging, combining tailored mechanical performance, superior moisture barriers, and non-migratory antimicrobial protection while maintaining compliance with food-contact regulations. </p></trans-abstract><kwd-group xml:lang="ru"><kwd>антибастерный отклик</kwd><kwd>свойства нанокомпозита</kwd><kwd>ПЭНП</kwd><kwd>наночастицы ZrО2</kwd></kwd-group><kwd-group xml:lang="en"><kwd>аntibасtеriаl response</kwd><kwd>nanocomposite properties</kwd><kwd>LDPE</kwd><kwd>ZrО2 nanoparticles</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Hsissou R, Seghiri R, Benzekri Z, Hilali M, Rafik M, Elharfi A. Polymer composite materials: A comprehensive review. 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