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Modification of asphaltic concrete with a mineral polymeric additive based on butadiene-styrene rubber and chemically precipitated calcium carbonate

https://doi.org/10.20914/2310-1202-2016-4-215-221

Abstract

Modification of asphaltic concrete with a mineral polymeric additive based on butadiene – styrene rubber and chemically precipitated calcium carbonate. This paper presents the results of the study of physical – mechanical and service properties of the asphaltic concrete modified with the mineral polymeric composition. Calcium carbonate is used both as a filler and a coagulant. The chalk was preliminarily ground and hydrophobizated by stearic acid. These operations contribute to even distribution of the filler and interfere with lump coagulation. As a result of the experiments, it was found that the best results were obtained by combining the operations of dispersion and hydrophobization. The optimal amount of stearic acid providing the finest grinding in a ball mill is a content from 3 to 5% by weight. The optimal grinding time of the filler was found (4–6 hours). With increasing dispersion time the particles form agglomerates. Filling the butadiene styrene latex with the hydrophobic fine-grained calcium carbonate was carried out in the laboratory mixer. As a result of the experimental works, it was found that the best distribution of the filler takes place with ratio of rubber: chalk – 100:400. The resulting modifier was subjected to the thermal analysis on the derivatograph to determine its application temperature interval. A marked reduction in weight of the mineral polymeric modifier begins at 350 °C. Thus, high temperature of the modifier destruction allows to use it at the temperature of the technological process of asphaltic concrete preparation (up to 170 °C). It was found that an increase in the amount of the carbonate filler in the rubber SKS 30АRК significantly increases its thermal resistance and connection of the polymer with the chalk in the composition.

About the Authors

S. I. Niftaliev
Voronezh state university of engineering technologies
Russian Federation

doctor of chemical sciences, professor, inorganic chemistry and chemical technology department, 

Revolution Av., 19 Voronezh, 394036



Y. S. Peregoudov
Voronezh state university of engineering technologies

candidate of chemical sciences, assistant professor, inorganic chemistry and chemical technology department, 

Revolution Av., 19 Voronezh, 394036



N. Horin
Voronezh state university of engineering technologies

student, inorganic chemistry and chemical technology department, 

Revolution Av., 19 Voronezh, 394036



Y. M. Nechesova
Voronezh state university of engineering technologies

student, inorganic chemistry and chemical technology department, 

Revolution Av., 19 Voronezh, 394036



References

1. 1 Bakaeva Y.V., Bogunov S. I., Lygina L. V., Niftaliyev S. I. et al. Study the effect of dispersion of chemically precipitated calcium carbonate on properties of PVC compounds. Izvestiya vuzov [News of higher educational institutions. Chemistry and chemial technology]. 2012. vol. 55. no. 2. pp. 64-66. (in Russian)

2. 2 Niftaliyev S. I., Malyavina Yu. M., PeregoDov Y. S., Korchagin V. I. Limiting factors of obtaining a hydrophobic filler based on chemically precipitated calcium carbonate. Kondensirovannye sredy [Condensed matter and interphase boundaries] 2013. vol. 15. no. 4. pp. 421-425. (in Russian)

3. 3 Kerber M. L., Bukanov, A. M., Vol'fson S. I. Fizicheskie I khimicheskie protsessy pri pererabotke [Physical and chemical processes in polymer processing] SaintPetersburg, Litografiya, 2013. 318 p (in Russian)

4. 4 Limper A. Mixing of Rubber Compounds. Munich, 2012. 252 p.

5. 5 Sommer G. Troubleshooting Rubber Problems. Cincinnati, 2014. 310 p.

6. 6 Prokopets V. S., Ivanova T. L. Modifikatsiya dorozhnogo asfal’tobetona [Modification of road asphalt rubber powders by mechanical alloying method for producing] Omsk, 2012. 125 p. (in Russian)


Review

For citations:


Niftaliev S.I., Peregoudov Y.S., Horin N., Nechesova Y.M. Modification of asphaltic concrete with a mineral polymeric additive based on butadiene-styrene rubber and chemically precipitated calcium carbonate. Proceedings of the Voronezh State University of Engineering Technologies. 2016;(4):215-221. (In Russ.) https://doi.org/10.20914/2310-1202-2016-4-215-221

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ISSN 2226-910X (Print)
ISSN 2310-1202 (Online)