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The use of plasticizing additives based on recycled raw materials in the petrochemical rubber mixtures

https://doi.org/10.20914/2310-1202-2016-4-201-206

Abstract

At present, the development of alternative products for elastomers based on recycling petrochemical raw materials is a new trend of the rubber industry progress. Petrochemical raw materials include spent lubricants and motor oils are among such recycling products. In this context, the influence of the products of recycling waste engine oil (DVCH and RA) in comparison with industrial oil (I-20) on the technological properties of filled elastomeric compositions was investigated. The elastomeric compositions were based on poly isoprene and divinyl rubbers. The plasticizing components were manufactured by IOOO “DVCH-Menedzhment”. They are mixture of hydro-carbons, C16–C20 and differ from each other in the content of linear and branched paraffin. Plastic-elastic properties of rubber compounds on the shear disk viscometer MV2000 in accordance with GOST 10722–76 was carried out. Kinetics of vulcanization on the rheometer ODR2000 according to GOST 12535–84 was defined. It is shown that the introduction of RA test plasticizing component provides a significant effect on Mooney viscosity, as compared to elastomeric compositions containing a plasticizer and I-20 and plasticizing additive DVCH. It revealed that the administration of all components in the studied plasticizing elastomer compositions based on a combination poly isoprene and divinyl rubbers has no significant effect on the rate of relaxation of stress of rubber compounds. It is found that elastomeric compositions containing as additives investigated processing waste oil products (DVCH and RA) are characterized by a slightly smaller value of time to reach an optimal degree of vulcanization.

About the Authors

Z. S. Shashok
Belarusian state technological university
Belarus

technology of petrochemical synthesis and polymer materials processing department, 

Sverdlova str., 13a Minsk, 220006



A. V. Leshkevich
Belarusian state technological university
Belarus

technology of petrochemical synthesis and polymer materials processing department,

Sverdlova str., 13a Minsk, 220006



N. V. Kruglik
CJS “Amkodor-Elastomer”
Belarus
Ponomarenko str., 7-4, Minsk, 220015


O. V. Karmanova
Voronezh state university of engineering technologies
Russian Federation

chemistry and chemical technology of organic compounds and polymers processing department, 

Revolution Av., 19, Voronezh, 394036



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Review

For citations:


Shashok Z.S., Leshkevich A.V., Kruglik N.V., Karmanova O.V. The use of plasticizing additives based on recycled raw materials in the petrochemical rubber mixtures. Proceedings of the Voronezh State University of Engineering Technologies. 2016;(4):201-206. (In Russ.) https://doi.org/10.20914/2310-1202-2016-4-201-206

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ISSN 2226-910X (Print)
ISSN 2310-1202 (Online)