Preview

Proceedings of the Voronezh State University of Engineering Technologies

Advanced search

The study of characteristics of powders of polymers for 3D printing

https://doi.org/10.20914/2310-1202-2017-4-157-164

Abstract

One of the biggest challenges is to find ways of recovering the expensive powder. With this aim, we needed to find out what happens with polyamide powder in the chamber of the printer and what processes affect raw materials, thereby impairing the physico-mechanical properties. In order to answer these questions, we conducted a number of studies. Articles of mixtures with a high aspect ratio of the secondary powder lose their properties: their surface is rough, increased fragility, there is a possibility of deformation of details. We carried out studies of the powder based on polyamide-12, applied by JSC "Center of technological competence of additive technologies" of the city of Voronezh, brand PA2200 modified. Material white powder, odourless. An increase in the degree of crystallinity from recycled polymer is considered an anomaly. But the violation of this trend due to the peculiarities of the technology of selective laser sintering. Thus, prolonged exposure of the powder in the chamber at a temperature close to the melting point, followed by a long cooling to room temperature represents the ideal conditions for the growth of crystalline phase. The research was able to identify differences due to deterioration of the physico-chemical properties of the powder after processing. The most important is the agglomeration of particles of the secondary powder in relation to the primary. In this regard, powder, already passed the stage of processing, an increase in the melting temperature, which causes defects in the fabricated parts: as the capacity of the carbon laser melting powder particles is fixed, its energy is not sufficient for the occurrence of the endothermic reaction caused by melting of the secondary powder. Thus, the powder particles only partially fused, whereby the resulting products of the observed increase in fragility.

About the Authors

Yu. F. Shutilin
Voronezh state university of engineering technologies
Dr. Sci. (Engin.), professor, department of chemistry and chemical technology organic compounds and polymer processing, Revolution Av., 19 Voronezh, 394036, Russia


M. S. Shcherbakova
Voronezh state university of engineering technologies
Cand. Sci. (Engin.), associate professor, department of chemistry and chemical technology organic compounds and polymer processing, Revolution Av., 19 Voronezh, 394036, Russia


V. V. Khripushin
air force Academy named after Professor N.E. Zhukovsky and Y.A. Gagarin
Cand. Sci. (Chem.), associate professor, department of physics and chemistry, Bolshevikov str., 54A, Voronezh, 394064, Russia


I. A. Borisova
Voronezh state university of engineering technologies)
master student, Department of chemistry and chemical technology organic compounds and polymer processing, Revolution Av., 19 Voronezh, 394036, Russia


References

1. Mengxue Y., Chang Z., Xiaoyong T. Design and Selective Laser Sintering of complex porous polyamide mould for pressure slip casting. Materials & Desingn. 2016. pp. 198–205.

2. Mys N., Verberckmoes A., Cardon L. Processing of Syndiotactic Polystyrene to Microspheres for Part Manufacturing through Selective Laser Sintering. Polymers. 2016. pp. 11–15.

3. Kumaresan, T., Gandhinathan R., Ramu M. Design, analysis and fabrication of polyamide/hydroxyapatite porous structured scaffold using selective laser sintering method for bio-medical applications. Journal of mechanical science and technology. 2016. pp.  5305–5312.

4. Miron-Borzan C.S., Dudescu M.C., Abd Elghany K. Analysis of Mechanical Proprieties of Selective Laser Sintered Polyamide Parts Obtained on Different Equipment. Materiale plastic. 2015. pp. 39–42.

5. Griffiths C.A., Howarth J., De Almeida-Rowbotham G.A design of experiments approach for the optimisation of energy and waste during the production of parts manufactured by 3D printing. Journal of cleaner production. 2016. pp. 74–85.

6. Gavrilin S.A. Method for recovering polymer powders. Patent № 2012053922, 2012.

7. Shutilin Yu.F. Fizikokhimiya polimerov [Physicalchemistry of polymers] Voronezh, Voronezh regional printing house, 2012. 840 p. (in Russian).

8. Hofland E.C., Baran I., Wismeijer D.A. Correlation of Process Parameters with Mechanical Properties of Laser Sintered PA12 Parts // Advances in materials science and engineering. 2017. P. 109–114.

9. Mainikova N.F., Koh-Tatarenko V. S., Zheltov, A.A., Reshetova A.D. et al. Study of wear resistance of polyamide. Potentsial sovremennoi nauki [Potential of modern science] 2017. no. 2 (28). pp. 14–18. (in Russian).

10. Davydov V.M., Morokov A.A. Laser machining of polyamide with a low-power laser. Uchenye zametki TOGU [Scientists notes of PNU] 2016. vol. 7. no. 4. pp. 445–448. (in Russian)


Review

For citations:


Shutilin Yu.F., Shcherbakova M.S., Khripushin V.V., Borisova I.A. The study of characteristics of powders of polymers for 3D printing. Proceedings of the Voronezh State University of Engineering Technologies. 2017;79(4):157-164. (In Russ.) https://doi.org/10.20914/2310-1202-2017-4-157-164

Views: 684


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 2226-910X (Print)
ISSN 2310-1202 (Online)