Reducing energy costs during solvent regeneration at the tar deasphalting unit
https://doi.org/10.20914/2310-1202-2021-2-202-207
Abstract
For propane tar deasphalting units, a rather high energy intensity of the technological process is characteristic. In order to reduce it, an assessment was made of the possibility of reducing the steam consumption during the regeneration of propane from asphalt solution. The study was carried out using a Honeywell UniSim Design modeling system, in which a model of a propane tar deasphalting unit was formed. The Peng-Robinson method was used as a mathematical package for calculating the thermodynamic properties of the components of the fractions. The component composition of the feedstock is represented by oil fractions with boiling points from 405 to 616 °C. When carrying out a computational experiment, the following values of technological parameters were used: the tar consumption was 38.9 t / h, the ratio (propane: raw material) was (6.4: 1), the yield of deasphalted oil was about 30 wt%. The performed analysis of a typical scheme for the regeneration of propane from asphalt solution showed that in the process stream supplied to the feed of the stripping column K-6, there is already a sufficiently large amount of a vapor phase consisting practically of propane and traces of oil fractions. To efficiently use the energy of the flow without attracting additional energy costs, it is advisable to separate the gas and liquid phases before they enter the column K-6, that is, to include an additional separator in the technological scheme before it. The performed computational experiment showed that in the proposed version of the technological scheme, the steam consumption required for the release of propane decreases by 17.5%, which, accordingly, for the subsequent devices of the scheme, reduces the amount of water discharged into the sewage system. Optimization of technological modes of the stripping column K-6 provides a clear separation of propane, in the flow of which the content of bitumen fractions is 0.03 mol%, which makes it possible in industrial conditions to return the flow of propane to the feed of the extraction column. The proposed technological solution for propane recovery can be used in the processes of one- and two-stage tar deasphalting.
About the Authors
A. V. MyasoedovRussian Federation
master student, chemistry and chemical technology department, st. Mironova, 5, Novokuibyshevsk, 446200, Russia
S. V. Popov
Cand. Sci. (Engin.), associate professor, chemistry and chemical technology department, st. Mironova, 5, Novokuibyshevsk, 446200, Russia
O. V. Khabibrakhmanov
Cand. Sci. (Chem.), associate professor, chemistry and chemical technology department, st. Mironova, 5, Novokuibyshevsk, 446200, Russia
References
1. Khalikova D.A., Petrov S.M., Bashkirtseva N.Yu. Review of promising technologies for processing heavy high-viscosity oils and natural bitumen. Bulletin of Kazan Technological University. 2013. vol. 16. no. 3. (in Russian).
2. Khairudinov I.R., Sultanov F.M., Kutin Yu.A., Tikhonov A.A. et al. The process of solvent deasphalting is a promising basis for achieving high depth of oil refining. World of oil products. Bulletin of oil companies. 2011. no. 3. pp. 17-19. (in Russian).
3. Magomedov R.N., Pripahaylo A.V., Maryutina T.A. Influence of iron oxide nanoparticles on the efficiency of solvent deasphalting of oil residue with subcritical pentane. Supercritical fluids: Theory and practice. 2019. vol. 14. no. 3. pp. 56-63. (in Russian).
4. Degtyarev P.A., Zamkovoy N.P., Shmakov N.V. Modernization of the tar deasphalting unit with propane 36/2 m of shop 101 of the oil plant of JSC "ANHK". Izvestiya vuzov. Applied Chemistry and Biotechnology. 2013. no. 2 (5). pp. 66–71. (in Russian).
5. Zabbarov R.R., Akhmitshin A.A., Valeeva N.G. Modeling the process of deasphalting natural bitumen and heavy oil residues. Bulletin of Kazan Technological University. 2013. no. 18. vol. 16. pp. 270–271. (in Russian).
6. Akhmetov A.F., Krasilnikova Yu.V., Gerasimova E.V. Features of processing heavy oil residues. Oil and Gas Business. 2011. vol. 9. no. 1. pp. 101. (in Russian).
7. Li L., Liu Y., Wu K., Liu C. et al. Catalytic solvent regeneration of a CO2?loaded MEA solution using an acidic catalyst from industrial rough metatitanic acid. Greenhouse Gases: Science and Technology. 2020. vol. 10. no. 2. pp. 449-460. doi: 10.1002/ghg.1839
8. Wang T., Yu W., Le Moullec Y., Liu F. et al. Solvent regeneration by novel direct non-aqueous gas stripping process for post-combustion CO2 capture. Applied Energy. 2017. vol. 205. pp. 23-32. doi: 10.1016/j.apenergy.2017.07.040
9. Leimbrink M., Sandk?mper S., Wardhaugh L., Maher D. et al. Energy-efficient solvent regeneration in enzymatic reactive absorption for carbon dioxide capture. Applied energy. 2017. vol. 208. pp. 263-276. doi: 10.1016/j.apenergy.2017.10.042
10. Bhatti U.H., Nam S., Park S., Baek I.H. Performance and mechanism of metal oxide catalyst-aided amine solvent regeneration. ACS Sustainable Chemistry & Engineering. 2018. vol. 6. no. 9. pp. 12079-12087. doi: 10.1021/acssuschemeng.8b02422
11. Sultanov F.M., Khairudinov I.R., Shoipov Kh.S., Nasyrov R.K. and others. Modernization of the block of solvent recovery from deasphalted solution at deasphalting units of 36/2, 36 / 2M type in order to reduce energy consumption. World of oil products. Bulletin of oil companies. 2014. no. 2. pp. 12-15. (in Russian).
12. Sultanov F.M., Akhmetov S.A., Sultanbaev A.Yu. Optimization of the basic unit for tar deasphalting. Network edition "Oil and Gas Business". 2014. no. 5. pp. 313-323. (in Russian).
13. Zamkovoy N.P., Smolyar A.V. Improving the efficiency of the tar deasphalting unit. Modern technologies and scientific and technical progress. 2019. vol. 1. pp. 15-16. (in Russian).
14. Zamkovoy N.P., Podoplelov E.V., Dementyev A.I. Increasing the efficiency of the propane tar deasphalting unit. Bulletin of the Angarsk State Technical University. 2019. vol. 1. no. 13. pp. 40-44. (in Russian).
15. Podzemelnov F.I., Korchagina T.K. Increasing the efficiency of the propane tar deasphalting unit. International Journal of Applied and Fundamental Research. 2017. no. 6-2. pp. 224-225. (in Russian).
16. Long J., Shen B., Ling H., Zhao J. Nonconventional vacuum residue upgrading blended with coal tar by solvent deasphalting and fluid catalytic cracking. Industrial & engineering chemistry research. 2012. vol. 51. no. 7. pp. 3058-3068. doi: 10.1021/ie202407u
17. Ruitian S., Dong L.I., Liangjun P.E.I., Yang Y.U.A.N. Effect of Deasphalting Solvent on Structure of Coal Tar Asphaltene. Acta Petrolei Sinica (Petroleum Processing Section). 2017. vol. 33. no. 6. pp. 1209.
18. Long J., Shen B., Zhao J., Ling H. et al. Mechanism of improving atmospheric solvent deasphalting process by vacuum residue blending with coal tar. Acta Petrolei Sinica (Petroleum Processing Section). 2012. vol. 1.
19. Shin S., Lee J.M., Hwang J.W., Jung H.W. et al. Physical and rheological properties of deasphalted oil produced from solvent deasphalting. Chemical Engineering Journal. 2014. vol. 257. pp. 242-247. doi: 10.1016/j.cej.2014.07.037
20. Magomedov R.N., Pripakhailo A.V., Maryutina T.A. Effect of the Phase State of the Solvent on Solvent Deactivation of Tar by n-Pentane. Chemistry and Technology of Fuels and Oils. 2019. vol. 54. no. 6. pp. 721-732. doi: 10.1007/s10553-019-00979-w
Review
For citations:
Myasoedov A.V., Popov S.V., Khabibrakhmanov O.V. Reducing energy costs during solvent regeneration at the tar deasphalting unit. Proceedings of the Voronezh State University of Engineering Technologies. 2021;83(2):202-207. (In Russ.) https://doi.org/10.20914/2310-1202-2021-2-202-207