Interaction researchepoxy binder with basalt by the X method
https://doi.org/10.20914/2310-1202-2022-3-172-176
Abstract
Basalt, known for its unique properties, is used for the production of yarns, fabrics, nets, and heat-insulating wool. Currently, a research is promoted on applicability of basalt as a dispersed filler for thermo- and rectoplastic materials without processing it into fibers. Therefore, investigation into interaction of epoxy binder with the crushed basalt is promising, which determines the aim of the given study. The objects of the research are the epoxy resin ED-20, polyethylene polyamine PEPA, and dispersed basalt filler. Spectrophotometer "Specord" with the IR-spectrum covering the area of 400 ÷ 4000 cm-1 was used to study the interaction of basalt filler with the epoxy oligomer and hardener. To take the photos of IR spectra of powders, the latter are pressed together with an excess of potassium bromide into tablets several millimeters thick. Special vacuum molds and pressure of several tons per 1 cm2 are used to produce the tablets. The ICS data confirm the interaction of ED-20 not only with PEPA, but also with the dispersed basalt. Amino groups, epoxy rings, CH groups of epoxy and aromatic rings of the binder and hardener undergo a reaction. As the content of the basalt filler in the epoxy increases, the same absorption maxima and bands are observed as in the IR spectra of the composite material with a low content of dispersed basalt. The difference is that the higher the basalt content in the epoxy matrix, the higher the relative intensity of such maxima, which indicates a stronger interaction of the components.
About the Authors
E. Y. Vasinkina
Saratov State Technical University named after Gagarin Yu.A.
Russian Federation
Russian Federation
assistant, electric power engineering and electrical engineering department, Politechnicheskaya str., 77, Saratov, 410054, Russia
Y. A. Kadykova
Saratov State Technical University named after Gagarin Yu.A.
Dr. Sci. (Engin.), associate professor, electric power engineering and electrical engineering department, Politech-nicheskaya str., 77, Saratov, 410054, Russia
S. G. Kalganova
Saratov State Technical University named after Gagarin Yu.A.
Dr. Sci. (Engin.), associate professor, electric power engineering and electrical engineering department, Politech-nicheskaya str., 77, Saratov, 410054, Russia
References
1. Bekeshev A.Z., Bredikhin P.A., Akmetova M.K., Kadykova Yu.A. Study of the properties of dispersed basalt and its influence on the characteristics of polyolefins. Polzunovskiy vestnik. 2017. no. 2. pp. 115–118. (in Russian).
2. Aidaraliev J.K., Atyrova R.S., Kainazarov A.T., Abdiev M.S. The technology of basalt fibers on bases of local basalts and prospects for application. Izvestiy Oshskogo technologicheskogo university. 2018. no. 1–1. pp. 251–258. (in Russian).
3. Malova Yu.G., Ablesimov N.E. Rocks of basalt composition: deposits. part II. Basalt technologies. 2014. pp. 26–24. (in Russian).
4. Pavlov V.V., Arzamastsev V.S., Levkina N.L., Arzamastsev S.V. Evaluation of the effectiveness of modifying polyamide 6 with basalt fillers. Plastic masses. 2015. no. 9-10. pp. 39-41. (in Russian).
5. Bagataev R.M. Study of igneous rocks of mountainous Dagestan for the production of basalt fiber. Eurasian Scientific Association. 2019. no. 1–2 (47). pp. 110–116. (in Russian).
6. Anosov VV, Akhylbek S. Application of basalt rocks for the production of fillers for composite materials. StudNet. 2021. vol. 4. no. 5. (in Russian).
7. Drozdyuk T.A., Aizenshtadt A.M., Makhova T.A., Frolova M.A. Evaluation of the suitability of basalts for the production of mineral fiber. Industrial and civil construction. 2018. no. 7. pp. 52–56. (in Russian).
8. Vasil'eva A.A., Pavlova M.S. Obtaining continuous basalt fiber based on basalt from the Vasilyevsky deposit. Technique and technology of silicates. 2019. vol. 26. no. 4. pp. 111–114. (in Russian).
9. Chimchikova M.K. Basalt and wollastonite as polymer matrix fillers. Bulletin of the Kyrgyz State University of Construction, Transport and Architecture. N. Isanova. 2021. no. 3 (73). pp. 423–428. (in Russian).
10. Imankulova A.S., Kurmanalieva A.K. Study of the physical and mechanical properties of composite materials using acrylic dispersions. Proceedings of the Kyrgyz State Technical University. I. Razzakova. 2020. no. 3 (55). pp. 217–224. (in Russian).
11. Ulegin S.V., Kadykova Yu.A., Farkhutdinova E.G., Sotnik V.A. Epoxy compounds filled with dispersed mineral filler. Chemistry: education, science, technology: collection of proceedings of the All-Russian scientific-practical conference with elements of a scientific school. MTsNIP, 2014. pp. 347. (in Russian).
12. Dzhigiris D.D., Makhova M.F. Fundamentals of the production of basalt fibers and products. Moscow, Teploenergetik, 2002. 416 p. (in Russian).
13. Kadykova Yu.A., Ulegin S.V., Farkhutdinova E.G., Sotnik V.A. Polymer matrix composite materials based on epoxy matrix filled with dispersed basalt. Bulletin of the Saratov State Technical University. 2012. vol. 4. no. 1 (68). pp. 97-99. (in Russian).
14. Tereshchenko Yu.V. Interpretation of the main indicators of heart rate variability. New medical technologies in the service of primary health care: materials of the interregional conference, Omsk, April 10–11, 2010. pp. 3–11. (in Russian).
15. Mostovoy A., Bekeshev A., Tastanova L., Akhmetova M. et al. The effect of dispersed filler on mechanical and physicochemical properties of polymer composites. Polymers and Polymer Composites. 2021. vol. 29. no. 6. pp. 583-590. doi: 10.1177/0967391120929040
16. Pakharenko V., Yanchar I., Efanova V. Polymer composite materials with fibrous and disperse basalt fillers. Fibre Chemistry. 2008. vol. 40. no. 3.
17. Vinay S.S., Sanjay M.R., Siengchin S., Venkatesh C.V. Basalt fiber reinforced polymer composites filled with nano fillers: A short review. Materials Today: Proceedings. 2021. doi: 10.1016/j.matpr.2021.10.430
18. Patti A., Nele L., Zarrelli M., Graziosi L. et al. A comparative analysis on the processing aspects of basalt and glass fibers reinforced composites. Fibers and Polymers. 2021. vol. 22. no. 5. pp. 1449-1459. doi: 10.1007/s12221-021-0184-x
19. Raajeshkrishna C.R., Chandramohan P., Babatunde Obadele A. Friction and thermo mechanical characterization of nano basalt reinforced epoxy composites. International Journal of Polymer Analysis and Characterization. 2021. vol. 26. no. 5. pp. 425-439. doi: 10.1080/1023666X.2021.1899692
20. Subagia I.D.G.A., Tijing, L.D., Kim Y., Kim C.S. et al. Mechanical performance of multiscale basalt fiber–epoxy laminates containing tourmaline micro/nano particles. Composites Part B: Engineering. 2014. vol. 58. pp. 611-617. doi: 10.1016/j.compositesb.2013.10.034
21.
Review
For citations:
Vasinkina E.Y., Kadykova Y.A., Kalganova S.G. Interaction researchepoxy binder with basalt by the X method. Proceedings of the Voronezh State University of Engineering Technologies. 2022;84(3):172-176. (In Russ.) https://doi.org/10.20914/2310-1202-2022-3-172-176
Views:
416
Email this article 
Post a Comment 
