Preview

Proceedings of the Voronezh State University of Engineering Technologies

Advanced search

Properties and structural features of epoxycomposites reinforced with modified PAN- flagellum

https://doi.org/10.20914/2310-1202-2022-4-200-205

Abstract

The performance characteristics of composite materials reinforced with polyacrylonitrile technical flagellum (PAN-TF), which has the reactivity of functional groups, can be improved by modifying it. The aim of the work was to study the effect of polyacrylonitrile fibrous materials, applied with AGM-9, A-187, A-174 and Duron OS 3151 modifiers, on the kinetics of the ED-20 epoxy resin curing process, structural features of the developed composites and their operational properties. The methods of kinetic research, differential scanning calorimetry (DSC), scanning electron microscopy and mechanical testing of composite materials were used in the work. The effect of modified PAN-TF on the change in the kinetics of the curing process of the epoxy binder is shown, characterized by an increase in the curing time, a decrease in the maximum curing temperature and a decrease in the activation energy of the curing ED-20. The results of kinetic studies are confirmed by the data of DSC epoxy compositions based on modified PAN-TF, which show a decrease in the maximum temperature and an increase in the thermal effects of the ED-20 curing process in the presence of the studied reinforcing systems compared with epoxy composite reinforced with unmodified flagellum. The structure formation of epoxy compositions under milder conditions ensures the formation of a contact zone between the elementary fibers and the binder, which contributes to an increase in the solidity of plastics compared to a composite based on the original PAN-TF. A comparative analysis of the strength properties of the studied composites showed that when applied to ED-20, there is an improvement in strength indicators. The assessment of kinetic parameters, structural features and strength properties of the developed composites reinforced with modified PAN-TF indicates an increase in the surface activity of fibrous materials as a result of their modification.

About the Authors

N. G. Zubova
Balakovo Institute of Engineering and Technology - branch of the National Research Nuclear University «MEPhI»
Russian Federation

Cand. Sci. (Engin.), assistant professor, department of physics and natural sciences, st. Chapaev, 140, Balakovo, Saratov region, 413800, Russia



V. M. Gerasimova
Balakovo Institute of Engineering and Technology - branch of the National Research Nuclear University «MEPhI»

Cand. Sci. (Engin.), assistant professor, department of physics and natural sciences, st. Chapaev, 140, Balakovo, Saratov region, 413800, Russia



N. L. Levkina
Engels Institute of Technology (branch) of Yu.A. Gagarin Saratov State Technical University

Cand. Sci. (Engin.), assistant professor, technology and equipment for chemical, oil and gas and food industries department, Svobody Square, 17, Engels, Saratov region, 413111, Russia



T. P. Ustinova
Engels Institute of Technology (branch) of Yu.A. Gagarin Saratov State Technical University

Dr. Sci. (Engin.), professor, technology and equipment for chemical, oil and gas and food industries department, Svobody Square, 17, Engels, Saratov region, 413111, Russia



K. B. Kostin
Yu.A. Gagarin Saratov State Technical University

Cand. Sci. (Engin.), senior researcher, scientific and educational center of nanotechnologies and nanomaterials, st. Polytechnic, 77, Saratov, 410054, Russia



References

1. Yang Z., Yao Y., Huang Y., Chen W., Dong X. Surface Modification Method of Polyacrylonitrile (PAN) Fibers by L-cysteine Coupling Protein. Fibers Polymers. 2019. vol. 20. pp. 2581–2586. doi: 10.1007/s12221–019–9343–8

2. Perepelkin K.E. Reinforcing fibers and fiberous polymeric composites. SPb, Scientific foundations and technologies, 2009. 380 p. (in Russian).

3. Khasanov O. Kh., Ismailov R.I. Modification of polyacrylonitrile fibers monomeric salts based on aminoalkyl acrylates with halogen containing substances. Proceedings of higher education institutions. Textile industry technology. 2021. no 1 (319). pp. 66–72. doi: 10.47367/0021–3497_2021_1_66 (in Russian).

4. Sunil S., Abhilas J.K., Kumar A., Shukla H.K. Oxidative Stabilization Studies on Pretreated Polyacrylonitrile Precursor Fiber Suitable For Carbon Fiber. Production. AIP Conference Proceedings, Published Online, 25 October, 2019. vol. 2166. Available at: https://doi.org/10.1063/1.5131605 (дата обращения 25.01.2023).

5. Zweifel H., Maier R.D., Schiller M. Plastcs Additives. Handbook. SPb: CEP "Profession", 2016. 1088 p. (in Russian).

6. Rogovina S.Z., Prut E.V., Berlin A.A. Composite Materials Based on Synthetic Polymers Reinforced with Natural Fibers. Polymer Science, Series A. 2019. vol. 61. pp. 417–438. doi: 10.1134/S0965545X19040084

7. Khandelwal S., Rhee K.Y. Recent advances in basalt-fiber-reinforced composites: Tailoring the fiber-matrix interface. Composites Part B: Engineering. 2020. vol. 192. pp. 1–13. doi: 10.1016/j.compositesb.2020.108011

8. Shapagin A.V. et al. Epoxyorganosilane Finishing Compositions for Fibrous Fillers of Thermosetting and Thermoplastic Binders. Polymers. 2022. vol. 14. no 1. pp. 59–73. doi: 10.3390/polym14010059

9. Rajan R. et al.Modification of epoxy resin by silane-coupling agent to improve tensile properties of viscose fabric composites. Polymer Bulletin. 2018. vol. 75. pp. 167–195. doi: 10.1007/s00289–017–2022–2

10. Musayeva A.Yu. et al. Properties of modified epoxy resins (Review). Sciences of Europe. 2018. No 33. Р. 22–29.

11. Rajan R. et al. Mechanical, Thermal and Burning Properties of Viscose Fabric Composites – Influence of Epoxy Resin Modification. Journal of Applied Polymer Science. 2018. vol. 135. no. 36. pp. 1134–1148.

12. Shcherbakov A.S., Mostovoy A.S., Yakovlev N.A. Arzamastsev S.V. Effect of Carbon Nanotube Functionalization on the Physicochemical and Mechanical Properties of Modified Fiber-Reinforced Composites Based on an Epoxy Resin. Russian Journal of Applied Chemistry. 2021. vol. 94. pp. 1080–1087. doi: 10.1134/S1070427221080097

13. Liu F., Shi Z., Dong Yu. Improved wettability and interfacial adhesion in carbon fibre/epoxy composites via an aqueous epoxy sizing agent. Composites Part A: Applied Science and Manufacturing. 2018. vol. 112. pp. 337–345. doi: 10.1016/j.compositesa.2018.06.026

14. Belgacemi R., Derradji M., Mehelli O., Trache D., Liu W., Wang J. Highly advanced phthalonitrile composites from epoxy-ended hyperbranched poly(trimellitic anhydride ethylene glycol) ester grafted basalt fibers. Polymer Composites. 2021. vol. 42. no 8. pp. 3882–3891. doi: 10.1002/pc.26100

15. Korchina L.V., Zubova N.G., Popova N.E., Ustinova T.P. Effect of polyacrylonitrile fibers modified by various chemical finishes on the hardening kinetics proprieties of an epoxide composite based on them. Fibre Chemistry. 2015. no 6. pp. 360–362. doi: 10.1007/s10692–015–9621–1

16. Zubova N.G., Ustinova T.P. Evaluation of the efficiency of the process of obtaining modified PAN-TF used in the technology of epoxy composites. Materials of the International Scientific and technical symposium «EESTE2021», Moscow, October 20–21, 2021. – pp. 297–300. doi: 10.37816/eeste2021–1–297–300. (in Russian).

17. Grellmann V., Seidler S. Polymer Testing. SPb: CEP "Profession", 2010. 720 p. (in Russian).

18. Blaznov А.N. et al.Study of physicomechanical behavior of binder based on Etal45M curing agent // South-Siberian Scientific Bulletin. 2019. no 3 (27). pp. 100–107. doi: 10.25699/SSSB.2019.27.37228 (in Russian).

19. Ngan N.V., Malaxovskii S.S., Kostromina N.V., Ivashkina V.N. Influence of the siliconorganic modificator for the curing of the curing of the epoxy oligomer // Russian Chemical Reviews. 2018. vol. XXXII. no 6. pp. 106–108. (in Russian).

20. Rydz J., Shishkova A., Eckstein A.A. Scanning Electron Microscopy and Atomic Force Microscopy: Topographic and Dynamical Surface Studies of Blends, Composites, and Hybrid Functional Materials for Sustainable Future. Advances in Materials Science and Engineering. 2019. vol. 2019. pp 1–16. doi: 10.1155/2019/6871785


Review

For citations:


Zubova N.G., Gerasimova V.M., Levkina N.L., Ustinova T.P., Kostin K.B. Properties and structural features of epoxycomposites reinforced with modified PAN- flagellum. Proceedings of the Voronezh State University of Engineering Technologies. 2022;84(4):200-205. (In Russ.) https://doi.org/10.20914/2310-1202-2022-4-200-205

Views: 291


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 2226-910X (Print)
ISSN 2310-1202 (Online)