Influence of environmentally friendly Phytonorman oils on the adhesive properties of frost-resistant rubbers based on nitrile butadiene rubber
https://doi.org/10.20914/2310-1202-2023-2-189-197
Abstract
The use of plasticizers based on esters of various acids most effectively improves the processing of rubber compounds and the frost resistance of NBR-based rubbers. In this work, as a plasticizer, products based on vegetable raw materials were tested - Phytonorman oils produced by the Biochemical Holding ORGKHIM, which are di- and triglycerides containing fatty acids of tall oil. Model rubber compounds based on BNKS-18AMN contained 10, 20, 30 wt. including eco-oils of the Phytonorman 212 and Phytonorman 213 brands, a mixture without oil and with 10 wt. including dibutyl phthalate (DBPh). To assess the effect of the type and dosage of eco-oils on the properties of rubbers and rubber compounds, methods for studying technological, physical-mechanical and adhesive properties were used. Determination of frost resistance, a comparison was made of methods for determining the glass transition temperature: differential scanning calorimetry (DSC) and thermomechanical analysis (TMA, Fourier). When using vegetable oils Phytonorman -212 and Phytonorman -213, the technological properties of rubber compounds are significantly improved compared to the mixture without oil and are on the same level with DBPH traditionally used in nitrile rubbers. It has been established that the introduction of Phytonorman 213 eco-oil into the formulations of rubber compounds based on BNKS 18AMN up to 10 wt. hours allows you to improve the technological parameters, as well as lower the glass transition temperature of rubber. At the same time, the physical and mechanical parameters and adhesive properties of vulcanizates are reduced by an average of 10%. It is also worth noting that rubbers with Phytonorman 213 oil are not inferior to nitrile rubbers with DBPh in terms of basic characteristics, and they are superior in adhesive properties by 27%.
About the Authors
I. I. Bobrova
M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University
Russian Federation
Russian Federation
graduate student, chair of chemistry and processing technology of elastomers, Vernadskogo Pr., 86 Moscow, 119571, Russia
S. V. Kotova
M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University
Cand. Sci. (Engin.), associate professor, chair of chemistry and processing technology of elastomers, Vernadskogo Pr., 86 Moscow, 119571, Russia
Y. A. Naumova
M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University
Dr. Sc. (Tech. Sc.), Professor, Chair of Chemistry and Processing Technology of Elastomers, Vernadskogo Pr., 86 Moscow, 119571, Russia
References
1. Dick D.S. How to improve rubber compounds. 1800 practical recommendations for solving problems; lane from English, ed. BL Smirnova. SPb.: Profession. 2016. (in Russian).
2. Pavlova V.V., Sokolova M.D., Fedorova A.F. The influence of the content and nature of the plasticizer on the properties of butadiene-nitrile rubber. Journal of the Siberian Federal University. Technics and techology. 2021. vol. 14. no. 2. pp. 222-232. (in Russian).
3. Ushmarin N.F., Egorov E.N., Koltsov N.I. Frost-resistant rubber based on a combination of nitrile butadiene and hydrin rubbers. News of higher educational institutions. Chemistry and chemical technology. 2017. vol. 60. no. 8. pp. 60-64. (in Russian).
4. Mukhin V.V., Petrova N.N. The use of mixtures of nitrile and diene rubbers as a basis for creating sealing rubbers for equipment operating in cold climates. Rubber and Rubber -2021: traditions and innovations: materials of the X All-Russian Conference. LLC Publishing House "KiR", 2021. pp. 75-76. (in Russian).
5. Pavlova V.V., Sokolova M.D., Fedorova A.F. The influence of the content and nature of the plasticizer on the properties of butadiene-nitrile rubber. Journal of the Siberian Federal University. Technics and techology. 2021. vol. 14. no. 2. pp. 222-232. (in Russian).
6. Bogomazova E.S., Minigaliev T.B. Study of the influence of the new softener Fitonorman 212 on the technological and vulcanization properties of tread rubber. Industrial production and use of elastomers. 2016. no. 2. pp. 13–15. (in Russian).
7. Orlova E.A. et al. Properties of rubber mixtures based on Fitonorman 212 and 213 in comparison with rapeseed oil. Rubber industry: raw materials, materials, technology. 2019. pp. 79–81. (in Russian).
8. Kotova S.V., Lyusova L.R., Naumova Yu.A. et al. Features of the use of PHYTONORMAN series oils in rubbers based on nitrile butadiene rubber BNKS 28 AMN. Rubber and Rubber. 2020. vol. 79. no. 3. pp. 134–139. (in Russian).
9. Koltsov N.I., Ushmarin N.F., Issakova S.A., Vinogorova S.S. Study of the influence of plasticizers PEF-1 and trichlorethyl phosphate on the technological, physical and mechanical properties and frost resistance of rubbers based on nitrile butadiene rubbers. Bulletin of the Kazan Technological University. 2012. vol. 15. no. 17.pp. 41-44. (in Russian).
10. Myasnikova N.S., Selyugina E.G. On the influence of interfacial interactions on the properties of rubbers based on nitrile butadiene rubbers. Vopr. Obor. Technicians. Ser. 15. Composite non-metallic materials in mechanical engineering. 2014. vol. 175. no. 4. pp. 28-33. (in Russian).
11. Alikberov A.S. et al. Features of vulcanization of new grades of non-woven materials. Rubber and Rubber. 1988. no. 5. pp. 16–18. (in Russian).
12. Shirokova E.S., Fomin S.V. Study of mass transfer of ester plasticizer in vulcanizates based on nitrile butadiene rubbers. Bulletin of the Kazan Technological University. 2008. no. 6. pp. 100-103. (in Russian).
13. Kontserenko M.V., Khristolubov A.A., Tyurina N.D., Efimov V.A. et al. Study of the viscosity properties of solutions of SKMS-30arkp rubber in dicyclopentadiene. News of higher educational institutions. Chemistry and chemical technology 2006. vol. 49. no. 3. pp. 50–52. (in Russian).
14. Dudina E.S., Medvedeva K.A., Cherezova E.N. Thermal analysis of the curing process and heat resistance of epoxyamine polymers modified with siloxane rubber destructors. Bulletin of the Technological University. 2018. vol. 21. no. 9. pp. 62-65. (in Russian).
15. Malysheva G.V., Akhmetova E.Sh., Shimina Yu.Yu. Estimation of phase transition temperatures of polymer binders using differential scanning calorimetry. Adhesives. Sealants. Technologies. 2014. no. 6. pp. 29-33. (in Russian).
16. Lopatina, S.S., Vaniev M.A., Sychev N.V., Savchenko Y.Yu. et al. Swelling of rubbers based on nitrile butadiene rubbers in aqueous solutions of sodium chloride at elevated temperatures. Industrial production and use of elastomers. 2019. no. 4. pp. 22-26. (in Russian).
17. Fedorova A.F., Davydova M.L., Shadrinov N.V., Borisova A.A. et al. Study of changes in the properties of sealing rubber under the influence of a hydrocarbon environment and temperature conditions. Natural resources of the Arctic and Subarctic. 2022. vol. 27. no. 2. pp.316-326. (in Russian).
18. Chaikun A.N., Venediktova M.A., Eliseev O.A., Naumov I.S. Study of fuel-resistant rubbers based on nitrile butadiene rubbers made with the use of various types of emulsifiers. Proceedings of VIAM. 2014. (in Russian).
19. Gorbovets M.A., Kochetkov D.A., Khodinev I.A. Analysis and comparison of Russian and foreign standards establishing test methods for thermomechanical fatigue. Proceedings of VIAM. 2014. (in Russian).
20. Papkov V.N., Yuryev A.N., Skachkov A.M., Rodnyansky D.A. et al. Development of optimal conditions for the production of nitrile-butadiene rubbers with increased frost resistance // Proceedings of VSUET. 2022. vol. 84. no. 1. pp. 32-34. (in Russian).
Review
For citations:
Bobrova I.I., Kotova S.V., Naumova Y.A. Influence of environmentally friendly Phytonorman oils on the adhesive properties of frost-resistant rubbers based on nitrile butadiene rubber. Proceedings of the Voronezh State University of Engineering Technologies. 2023;85(2):189-197. (In Russ.) https://doi.org/10.20914/2310-1202-2023-2-189-197
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