Investigation of film materials obtained from modified polyvinyl al-cohol-based solution systems
https://doi.org/10.20914/2310-1202-2023-2-226-236
Abstract
Films based on PVA solutions are currently attracting increasing attention due to their high transparency, barrier properties and environmentally friendly nature. This is due to the fact that PVA films have greater flexibility, transparency, impact strength and lower cost than other packaging materials. When discarded, PVA can decompose in the natural environment without adding to the pollution. The article is devoted to the study of film materials obtained from modified solution systems based on polyvinyl alcohol (PVA). Polyvinyl alcohol grade 098–10 was used as the starting product; glycerin grade T 94 was used as a plasticizer. The films were cast on glass, then heated in a heating cabinet at a temperature of 90 °C for 31 hours. The influence of different concentrations of PVA solutions on the barrier (vapor permeability) and physical and mechanical properties of films was studied. It was shown that, with an increase in the concentration of glycerol in PVA, the fracture resistance increased, the relative elongation noticeably decreased, and the permeability of the polymer sharply increased. The introduction of 20–30% plasticizer into PVA resulted in the production of a sufficiently elastic film, an increase in elongation at break, and also a decrease in tensile strength. The complex of studies carried out made it possible to determine the influence of modifying additives on the structural transformations of PVA compositions for the creation of new generation coatings. In the future, it is planned to continue research on this topic, in particular on optimizing the temperature-time regime of coating formation
About the Authors
M. I. GubanovaRussian Federation
Cand. Sci. (Engin.), associate professor, industrial design, packaging technology and expertise department, 11, Volokolamsk sh., Moscow, 125080, Russia
N. S. Bazhenov
graduate student, industrial design, packaging technology and expertise department, 11, Volokolamsk sh., Moscow, 125080, Russia
I. A. Kirsh
Dr. Sci. (Chem.), associate professor, industrial design, packaging technology and expertise department, 11, Volokolamsk sh., Moscow, 125080, Russia
O. A. Bannikova
,, industrial design, packaging technology and expertise department, 11, Volokolamsk sh., Moscow, 125080, Russia
V. A. Dymitsky
graduate student, industrial design, packaging technology and expertise department, 11, Volokolamsk sh., Moscow, 125080, Russia
References
1. Babin A.N., Guseva M.A. Using the rheological method to study the solubility of components in a polymer binder. Proceedings of VIAM. 2016. 2016. no. 6 (42). pp. 36-43. doi: 10.18577/2307–6046–2016–0–6–5–5 (in Russian).
2. Kabat O.S., Kharchenko B.G., Derkach A.D., Artemchuk V.V. and others. Polymer composite materials based on fluoroplastic and the method of their production. Questions of Chemistry and Chemical Technology. 2019. no. 3. pp. 116-122. doi: 10.32434/0321–4095–2019–124–3–116–122 (in Russian).
3. Kablov E.N. What will the future be made of? New generation materials, technologies for their creation and processing are the basis of innovation. Wings of the Motherland. 2016. no. 5. pp. 8–18. (in Russian).
4. Kablov E.N. New generation materials are the basis of innovation, technological leadership and national security of Russia. Intelligence and technology. 2016. no. 2. pp. 16–21. (in Russian).
5. Andrade J., González-Martínez C., Chiralt A. Antimicrobial PLA-PVA multilayer films containing phenolic compounds. Food Chemistry. 2022. no. 375. doi: 10.1016/J.FOODCHEM.2021.131861
6. Audic J., Chaufer B. Influence of plasticizers and crosslinking on the properties of biodegradable films made from sodium caseinate. Eur Polym J 2005. vol. 41. no. 8. pp. 1934–42. doi: 10.1016/j.eurpolymj.2005.02.023
7. Averous L., Boquillon N. Biocomposites based on plasticized starch: thermal and mechanical behaviours. Carbohydrate polymers. 2004. vol. 56. no. 2. pp. 111-122. doi: 10.1016/j.carbpol.2003.11.015
8. Bergo P., Sobral PJA. Effects of plasticizer on physical properties of pigskin gelatin films. Food Hydrocolloids. 2007. vol. 21. no. 8. pp. 1285–1289. doi: 10.1016/j.foodhyd.2006.09.014
9. Bergo P.V.A., Carvalho R.A., Sobral P.J.A., dos Santos R.M.C. et al. Physical properties of edible films based on cassava starch as affected by the plasticizer concentration. Packaging Technology and Science. 2008. vol. 21. no. 2. pp. 85–89. doi: 10.1002/pts.781
10. Bertan L.C., Tanada-Palmu P.S., Siani A.C., Grosso C.R.F. Effect of fatty acids and “Brazilian elemi” on composite films based on gelatin. Food Hydrocolloids. 2005. vol.19. no. 1. pp. 73–82. doi: 10.1016/j.foodhyd.2004.04.017
11. Bordes P., Pollet E., Avérous L. Nano-biocomposites: biodegradable polyester/nanoclay systems. Progress in Polymer Science. 2009. vol. 34. no. 2. pp. 125–155. doi:10.1016/j.progpolymsci.2008.10.002
12. Fan K., Zhang M., Jiang F. Ultrasound treatment to modified atmospheric packaged fresh-cut cucumber: Influence on microbial inhibition and storage quality. Ultrasonics Sonochemistry. 2019. no. 54. pp. 162–170. doi:10.1016/j.ultsonch.2019.02.003
13. Garcia M.A., Martino M.N., Zaritzky N.E. Lipid Addition to Improve Barrier Properties of Edible Starch-based Films and Coatings. Journal of Food Science. 2000. vol. 65. no. 6. pp. 941–944. doi:10.1111/j. 1365–2621.2000.tb09397.x
14. Hemmatgir F., Koupaei N., Poorazizi E. Characterization of a novel semi-interpenetrating hydrogel network fabricated by polyethylene glycol diacrylate/polyvinyl alcohol/tragacanth gum as a wound dressing. Burns. 2022. vol. 48. no. 1. pp. 146–155. doi: 10.1016/J.BURNS.2021.04.025
15. Hu H., Yong H., Yao X., Chen D. et al. Effect of starch aldehyde-catechin conjugates on the structural, physical and antioxidant properties of quaternary ammonium chitosan/polyvinyl alcohol films. Food Hydrocolloids. 2022. vol. 124. doi: 10.1016/J.FOODHYD.2021.107279
16. Jongjareonrak A., Benjakul S., Visessanguan W., Tanaka, M. Effects of plasticizers on the properties of edible films from skin gelatin of bigeye snapper and brownstripe red snapper. European Food Research and Technology. 2005. vol. 222. no. 3–4. pp.229–235. doi:10.1007/s00217–005–0004–3
17. Kan J., Liu J., Xu F., Yun D. et al. Development of pork and shrimp freshness monitoring labels based on starch/polyvinyl alcohol matrices and anthocyanins from 14 plants: A comparative study. Food Hydrocolloids. 2022. vol. 124. doi. 10.1016/J.FOODHYD.2021.107293
18. Kariminejad M., Zibaei R., Kolahdouz-Nasiri A., Mohammadi R. et al. Chitosan/polyvinyl alcohol/SiO2 nanocomposite films: Physicochemical and structural characterization. Biointerface Research in Applied Chemistry. 2022. vol. 12. no. 3. pp. 3725–3734. doi: 10.33263/BRIAC123.37253734
19. Karnnet S., Potiyaraj P., Pimpan V. Preparation and properties of biodegradable stearic acid-modified gelatin films. Polym Degrad Stab. 2005. vol. 90. no. 1. pp. 106–10. doi:10.1016/j.polymdegradstab.2005.02.016
20. Ling H., Shen Y., Xu L., Pan H. et al. Preparation and characterization of dual-network interpenetrating structure hydrogels with shape memory and self-healing properties. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2022. pp. 636. doi: 10.1016/J.COLSURFA.2021.128061
21. Lu S., Tao J., Liu X., Wen Z. Baicalin-liposomes loaded polyvinyl alcohol-chitosan electrospinning nanofibrous films: Characterization, antibacterial properties and preservation effects on mushrooms. Food Chemistry. 2022. vol. 371. doi: 10.1016/J.FOODCHEM.2021.131372
22. MA X. The plastcizers containing amide groups for thermoplastic starch. Carbohydrate Polymers. 2004. vol. 57. no. 2. pp. 197–203. doi:10.1016/j.carbpol.2004.04.012
23. Pashova S., Radev R., Dimitrov G. Physical properties of edible films with different composition. Calitatea. 2019. vol. 20. no. 171. pp. 152-156.
24. Rhim J.–W., Park H.–M., Ha C.–S. Bio-nanocomposites for food packaging applications. Progress in Polymer Science. 2013. vol. 38. no. 10–11. pp. 1629–1652. doi:10.1016/j.progpolymsci.2013.05.008
25. Sau S., Kundu S. Variation in structure and properties of poly(vinyl alcohol) (PVA) film in the presence of silver nanoparticles grown under heat treatment. Journal of Molecular Structure. 2022. vol. 1250. doi: 10.1016/J.MOLSTRUC.2021.131699.
26. Shaikh H.M., Pandare K.V., Nair G., Varma A.J. Utilization of sugarcane bagasse cellulose for producing cellulose acetates: Novel use of residual hemicellulose as plasticizer. Carbohydrate Polymers. 2009. vol. 76. no. 1. pp. 23–29. doi: 10.1016/j.carbpol.2008.09.014
27. Singha P., Rani R., Badwaik L.S. Sweet lime peel-, polyvinyl alcohol – and starch-based biodegradable film: preparation and characterization. Polymer Bulletin. 2022. doi: 10.1007/S00289–021–04040 X
28. Sobral PJA., Santos JS., García FT., Effect of protein and plasticizer concentrations in film forming solutions on physical properties of edible films based on muscle proteins of a Thai Tilapia. J Food Eng. 2005. vol. 70. no. 1. pp. 93–100. doi: 10.1016/j.jfoodeng.2004.09.015
29. Suhag A., Biswas K., Singh S., Kulshreshtha A. Crosslinking effect on polyvinyl alcohol resin for barrier properties of barrier biaxial orientation films. Progress in Organic Coatings. 2022. vol. 163. doi: 10.1016/J.PORGCOAT.2021.106662
30. Suyatma N.E., Tighzert L., Copinet A., Coma V. Effects of hydrophilic plasticizers on mechanical, thermal, and surface properties of chitosan films. Journal of Agricultural and Food Chemistry. 2005. vol. 53. no. 10. pp. 3950–3957. doi:10.1021/jf048790
31. Tharanathan R.N. Biodegradable films and composite coatings: past, present and future. Trends in food science & technology. 2003. vol. 14. no. 3. pp. 71–78. doi:10.1016/S0924–2244(02)00280–7
32. Thulasisingh A., Kumar K., Yamunadevi B., Poojitha N. et al. Biodegradable packaging materials. Polymer Bulletin. 2021. pp. 15–23. doi:10.1007/s00289–021–03767 x
33. Vieira M.G.A., da Silva M.A., dos Santos L.O., Beppu M.M. Natural-based plasticizers and biopolymer films: A review. European Polymer Journal. 2011. vol. 47. no. 3. pp. 254–263. doi:10.1016/j.eurpolymj.2010.12.011
34. Wang Q., Chen W., Zhu W., McClements D.J. et al. A review of multilayer and composite films and coatings for active biodegradable packaging. Npj Science of Food. 2022. vol. 6. no. 1. doi:10.1038/s41538–022–00132–8
35. Wang Y., Zhang J., Zhang L. An active and pH-responsive film developed by sodium carboxymethyl cellulose/polyvinyl alcohol doped with rose anthocyanin extracts. Food Chemistry. 2022. vol. 373. doi: 10.1016/J.FOODCHEM.2021.131367
36. Wittaya T. Protein-Based Edible Films: Characteristics and Improvement of Properties. Structure and Function of Food Engineering. 2012. doi:10.5772/48167
37. Xie J., Wang R., Li Y., Ni Z. et al. A novel Ag2O-TiO2 Bi2WO6/polyvinyl alcohol composite film with ethylene photocatalytic degradation performance towards banana preservation. Food Chemistry. 2022. vol. 375. doi: 10.1016/J.FOODCHEM.2021.131708
38. Xie Y., Pan Y., Cai P. Hydroxyl crosslinking reinforced bagasse cellulose/polyvinyl alcohol composite films as biodegradable packaging. Industrial Crops and Products. 2022. vol. 176. doi: 10.1016/J.INDCROP.2021.114381
39. Zhang X., Zou W., Xia M., Zeng Q. et al. Intelligent colorimetric film incorporated with anthocyanins-loaded ovalbumin-propylene glycol alginate nanocomplexes as a stable pH indicator of monitoring pork freshness. Food Chemistry. 2022. vol. 368. doi: 10.1016/J.FOODCHEM.2021.130825
40. Zhang Y., Gao Q., Zhang S., Fan X. et al. rGO/MXene sandwich-structured film at spunlace non-woven fabric substrate: Application to EMI shielding and electrical heating. Journal of Colloid and Interface Science. 2022. vol. 614. pp. 194–204. doi: 10.1016/J.JCIS.2022.01.030
41. Zhao R., Guan W., Zheng P., Tian F. et al. Development of edible composite film based on chitosan nanoparticles and their application in packaging of fresh red sea bream fillets. Food Control. 2022. vol. 132. doi: 10.1016/J.FOODCONT.2021.108545
42. Zheng L., Liu L., Yu J., Shao P. Novel trends and applications of natural pH-responsive indicator film in food packaging for improved quality monitoring. Food Control. 2022. vol. 134. doi: 10.1016/J.FOODCONT.2021.108769
Review
For citations:
Gubanova M.I., Bazhenov N.S., Kirsh I.A., Bannikova O.A., Dymitsky V.A. Investigation of film materials obtained from modified polyvinyl al-cohol-based solution systems. Proceedings of the Voronezh State University of Engineering Technologies. 2023;85(2):226-236. (In Russ.) https://doi.org/10.20914/2310-1202-2023-2-226-236