Preview

Proceedings of the Voronezh State University of Engineering Technologies

Advanced search

Aspects of the directional synthesis of carbon nanotubes to create hierarchical radio-absorbing composite materials

https://doi.org/10.20914/2310-1202-2018-4-337-343

Abstract

The conducted information review showed that there are various types of radio absorbing materials.  The expansion of the working wavelength range for radio-absorbing composites is possible due to the combined use of conductive fillers, characterized by different magnetic and dielectric characteristics and the value of electrical conductivity.  As a rule, the increase in the efficiency of radio absorption of materials is associated with an increase in the concentration of metal fillers in them, as a result of which the weight and size parameters increase proportionally.  To avoid this, the use of carbon nanomaterials, which have the ability to create self-organizing hierarchical structures in the bulk of the composite, allows.  Varying the composition of the catalytic systems of the CVD process allows directional synthesis of carbon nanomaterials with the necessary morphological characteristics.  To assess the effect of the composition of the catalyst on the morphology and structure of the synthesized CNTs, 3 Ni / MgO catalyst compositions with different contents of the active component (Ni) were selected.  The effectiveness of the obtained catalysts was determined by the specific yield of CNTs (gC/gkat).  The morphology and structure of the catalysts and the synthesized CNTs were studied by means of scanning by transmission electron microscopy. The use of a nickel-based catalyst provides the material with magnetic properties.  The diameter of carbon filiform formations synthesized on Ni/0.16MgO and Ni / 0.3MgO catalysts is ~ 30 ÷ 60 nm.  The Ni/0.5MgO system is characterized by low productivity in one-dimensional nanostructures; the sample after the CVD process contains a large number of unstructured forms of carbon and an unchanged catalyst.  Structural diversity in carbon nanomaterials allows to obtain on their basis an effective hierarchical structure in the radio absorbing composite..

About the Authors

A. V. Shchegolkov
Tambov State Technical University
Russian Federation
Cand. Sci. (Engin.), associate professor, department of technique and production technology of nanoproducts, Technical University, Sovetskaya str., 106,


A. V. Shchegolkov
Tambov State Technical University
graduate student, department of technique and production technology of nanoproducts, Technical University, Sovetskaya, 106


I. D. Parafimovich
A.N. Sevchenko Institute of Applied Physical Problems of Belarussian State University
junior researcher, laboratoty of elioniks, Kurchatova Av., 7, 220045, Belarus


E. A. Burakova
Tambov State Technical University
Cand. Sci. (Engin.), associate professor, department of technique and production technology of nanoproducts, Sovetskaya, 106, Tambov, 392000, Russia


A. V. Kobelev
Tambov State Technical University
Cand. Sci. (Engin.), associate professor, department of electrical power engineering, Sovetskaya str., 106, Tambov, 392000, Russia


T. P. Dyachkova
Tambov State Technical University
Dr. Sci. (Chem.), professor, department of technique and production technology of nanoproducts, Sovetskaya str., 106, Tambov, 392000, Russia


References

1. Smirnov D.O. Kompozicionnye radiopoglosh-chayushchie materialy na osnove ferrimagnitnyh soedinenij [Composite radio-absorbing materials on the basis of ferrimagnetic compounds]. Moscow, 2009. 176 p. (in Russian).

2. Abrashova E.V., Gracheva I.E., Moshnikov V.A. Functional nanomaterials based on metal oxides with hierarchical structure. Journal of Physics: Conference Series. 2013. vol. 461. no. 1. pp. 012019. doi: 10.1088/1742–6596/461/1/012019

3. Kovneristiy Yu.K., Lazareva I.Yu., Ravaev A.A. Materialy, pogloshchayushchie SVCH-izlucheniya. [Materials absorbing microwave radiation]. Moscow, Nauka, 1982. 164 p. (in Russian).

4. Bogoroditsky N.P. Ehlektrotekhnicheskie materialy [Electrotechnical materials]. Leningrad, Energy, 1977. 352 p. (in Russian).

5.

6. Tareev B.M., Korotkov N.V., Petrov V.M. et al. Ehlektroradiomaterialy [Electroradiomaterials]. Moscow, Higher School, 1976. 336 p. (in Russian).

7. Ufimtsev P.Ya. Metod kraevyh voln v fizicheskoj teorii difrakcii [Edge wave method in the physical theory of diffraction]. Moscow, Soviet radio, 1962. 243 p. (in Russian).

8. Rozanov. N. Fundamental restriction for the width of the working range of radio-absorbing coatings. Radiotekhnika i ehlektronika [Radio Engineering and Electronics]. 1999. vol. 44. no. 5. pp. 526–530. (in Russian).

9. Gao J., Li Ch., Shilpakar U., Shen Y. Improvements of mechanical properties in dissimilar joints of HDPE and ABS via carbon nanotubes during friction stir welding process. Materials and Design. 2015. vol. 86. pp. 289–296. doi: 10.1016/j.matdes.2015.07.095

10. Chen J., Hutchings I.M., Deng T., Bradley M.S.A. et al. The effect of carbon nanotube orientation on erosive wear resistance of CNT-epoxy based composites. Carbon. 2014. vol. 73. pp. 421–431. doi: 10.1016/j.carbon.2014.02.083

11. Al-Saleh M.H., Al-Anid H.K., Hussain Y.A. CNT/ABS nanocomposites by solution processing: Proper dispersion and selective localization for low percolation threshold. Composites: Part A. 2013. vol. 46. pp. 53–59. doi: 10.1016/j.compositesa.2012.10.010

12. Bauhofer W., Kovacs J.Z. A Review and Analysis of Electrical Percolation in Carbon Nanotube Polymer Composites. Composites Science and Technology. 2009. vol. 69. pp. 1486–1498. doi: 10.1016/j.compscitech.2008.06.018

13. Bychanok D., Gorokhov G., Meisak D., Plyushch A. et al. Exploring Carbon Nanotubes/BaTiO3 /Fe3O4 Nanocomposites as Microwave Absorbers. Progress In Electromagnetics Research C. 2016. vol. 66. pp. 77–85. doi:10.2528/PIERC16051106


Review

For citations:


Shchegolkov A.V., Shchegolkov A.V., Parafimovich I.D., Burakova E.A., Kobelev A.V., Dyachkova T.P. Aspects of the directional synthesis of carbon nanotubes to create hierarchical radio-absorbing composite materials. Proceedings of the Voronezh State University of Engineering Technologies. 2018;80(4):337-343. (In Russ.) https://doi.org/10.20914/2310-1202-2018-4-337-343

Views: 778


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 2226-910X (Print)
ISSN 2310-1202 (Online)