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PROTECTIVE TREATMENT OF WOOD IMPREGNATING COMPOSITION OF PETROCHEMICAL WASTE

https://doi.org/10.20914/2310-1202-2015-1-170-174

Abstract

The paper presents results of experimental and theoretical studies aimed at expanding the applications of the copolymers on the basis of the waste styrene production. One of the areas is used as impregnating compositions of wood materials, selection of optimal conditions modification on samples of the most widely used in the industry of wood, such as birch, aspen and other. Studies were conducted to obtain and use an impregnating compositions based on copolymers synthesized from waste products of styrene and the cubic remainder rectification of ethylbenzene (CRRE) for the protective treatment of birch wood. Identified physic-chemical characteristics of physical mixtures of copolymers «CORS», «STAM», CRRE at different ratios. Studied the process of modification birch using the method of experiment planning greco-latin square of the fourth order, and the influence of such factors as the temperature of the impregnating composition, the duration of the impregnation, the temperature and duration of thermal treatment on the performance moisture resistance of wood. Were established optimal conditions modification birch wood treated impregnating compositions on the basis of physical mixtures of copolymer «CORS» with CRRE and copolymer «STAM» with CRRE is the mixing ratio 2:1, the duration and temperature of the impregnation 7 h and 95 0C, time and temperature of heat treatment 7 h and 170 0C, respectively. A sealing composition containing CRRE with copolymer «STAM» 1:2 is more preferable, as in the structure of the copolymer «STAM» contains carboxyl and anhydrite group. Thus was justified use for the modification of natural wood impregnating compositions on the basis of physical mixtures of CRRE with copolymers «CORS» and «STAM», which improve the properties of wood, increase moisture and weather resistance more than twice.

About the Authors

T. V. Maslakova
Voronezh state university of engineering technologies
Russian Federation
Senior teacher, Departament of engineering ecology


O. N. Filimonova
Voronezh state university of engineering technologies
Russian Federation
Professor, Departament of engineering ecology


S. S. Nikulin
Voronezh state university of engineering technologies
Russian Federation
Professor, Departament of technology of organic synthesis and macromolecular compounds


N. S. Nikulina
Voronezh Institute of state fire service of the Ministry of emergency situation
Russian Federation
Teacher, Department of fire safety of technological processes


References

1. Rasev A.I., Kosarin A.A. Gidrotermicheskaya obrabotka i konservirovanie drevesiny [Hydrothermal processing and preserving of wood]. Moscow, Forum, 2010. 416 p. (In Russ.).

2. Kalnin’sh A. Ya. Konservirovanie i zashchita lesomaterialov [Preservation and protection of timber]. Moscow, Lesnaya promyshlennost’, 1971. 423 p. (In Russ.).

3. Gorshin S.N. Konservirovanie lesomaterialov [Preservation of wood]. Moscow, Lesnaya promyshlennost’, 1977. 336 p. (In Russ.).

4. Nikulin S.S. Fiziko-mekhanicheskie svoistva drevesiny modifitsirovannoi sopolimerami na osnove otkhodov neftekhimii [Physicomechanical properties of wood modified copolymers based on waste petrochemicals]. Voronezh, VGLTA, 2004. 7 p. (In Russ.).

5. Tutorskii I.A., Potapov E.E., Shvartz A.G. Khimicheskaya modifikatsiya elastomerov [Chemical modification of elastomers]. Moscow, Khimiya, 1993. 304 p. (in Russ.).

6. Filimonova O.N. Pererabotka i primenenie kubovykh ostatkov rektifikatsii stirola [Processing and application of the bottoms of the distillation of styrene: the monograph]. Moscow, Akademiya Estestvoznaniya, 2009. 76 p. (In Russ.).

7. Khrulev V.M., Mashkin N.A., Dorofeev N.S. Modifitsirovannaya drevesina i ee primenenie [Modified wood and its application]. Novosibirsk, NISI, 1988. 120 p. (in Russ.).

8. Shamayev V.A., Nikulina N.S., Medvedev V.A. Modifitsirovanie drevesiny [Modification of wood]. Moscow, FLINTA, Nauka, 2013. 448 p. (in Russ.).

9. Dmitrenkov A.I., Nikulin S.S., Sakhokia I.A., Khokhlova O.A. Optimization of the processes of impregnation of wood waste petrochemical and pulp. Tez. dokl. mezhdunar. nauch.-tekhn. konf. “Sotsial’no-ekonomicheskie i ekologicheskie problem lesnogo kompleksa” [Proc. rep. Intern. scientific and engineering. Conf. "Socio-economic and environmental problems of forestry complex."]. Ekaterinburg, 1999. p. 181. (in Russ.).

10. Grachev Yu.P. Plaksin Yu.M. Matematicheskie metody planirovanie eksperimenta [Mathematical methods of experiment planning]. Moscow, Delhi-print, 2005. 296 p. (in Russ.).

11. Bogomolov B.D. Khimiya drevesiny i osnovy khimii vysokomolekulyarnykh soedinenii [Chemistry of wood and the basics of chemistry of high-molecular compound]. Moscow, Lesnaya promyshlennost’, 1973. 400 p. (in Russ.).

12. Nikulin S.S., Sakhokia I.A., Dmitrenkov A.I. et al. Copolymers on the basis of the bottoms of the distillation of styrene – modifiers wood. Izvestiya vuzov. Lesnoi zhurnal. [Bulletin of higher education institutions. Forest journal], 2002, no. 2, pp. 78-85. (In Russ.).


Review

For citations:


Maslakova T.V., Filimonova O.N., Nikulin S.S., Nikulina N.S. PROTECTIVE TREATMENT OF WOOD IMPREGNATING COMPOSITION OF PETROCHEMICAL WASTE. Proceedings of the Voronezh State University of Engineering Technologies. 2015;(1):170-174. (In Russ.) https://doi.org/10.20914/2310-1202-2015-1-170-174

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ISSN 2226-910X (Print)
ISSN 2310-1202 (Online)